Search for: All records

The tropical Pacific warming pattern since the 1950s exhibits two warming centers in the western Pacific (WP) and eastern Pacific (EP), encompassing an equatorial central Pacific (CP) cooling and a hemispheric asymmetry in the subtropical EP. The underlying mechanisms of this warming pattern remain debated. Here, we conduct ocean heat decompositions of two coupled model large ensembles to unfold the role of wind-driven ocean circulation. When wind changes are suppressed, historical radiative forcing induces a subtropical northeastern Pacific warming, thus causing a hemispheric asymmetry that extends toward the tropical WP. The tropical EP warming is instead induced by the cross-equatorial winds associated with the hemispheric asymmetry, and its driving mechanism is southward warm Ekman advection due to the off-equatorial westerly wind anomalies around 5°N, not vertical thermocline adjustment. Climate models fail to capture the observed CP cooling, suggesting an urgent need to better simulate equatorial oceanic processes and thermal structures.

 

El Niño–Southern Oscillation (ENSO) is an important but not the only source of interannual variability over the Indo–western Pacific. Non-ENSO forced variability in the region has received recent attention because of the implications for rainy-season prediction. Using a 35-member CESM1 Large Ensemble (CESM-LE) and 30 CMIP6 models, this study shows that the ensemble means project intensified interannual variability for precipitation, low-level winds, and sea level pressure under global warming, associated with the enhanced large-scale anomalous anticyclone (AAC) over the tropical northwestern (NW) Pacific after the ENSO signal is removed. A decomposition based on the column water vapor budget reveals that enhanced precipitation variability is due to the increased background specific humidity. The resultant anomalous diabatic heating intensifies the AAC, which further strengthens the precipitation anomalies. Over the tropical NW Pacific, the wind-induced evaporative cooling on the southeastern flank of the AAC is countered by the increased shortwave radiation due to the strengthened precipitation reduction. Tropospheric temperature anomalies in the ensemble means show no significant change, suggesting no apparent change of the interbasin positive feedback between the AAC and northern Indian Ocean SST. Intermodel analysis based on CMIP6 reveals that models with a larger increase in ENSO-unrelated precipitation variability over the NW Pacific are associated with stronger background warming in the eastern equatorial Pacific, due to the modulated Walker and Hadley circulations.

 

Molecular quasiparticle and excitation energies determine essentially the spectral characteristics measured in various spectroscopic experiments. Accurate prediction of these energies has been rather challenging for ground-state density functional methods, because the commonly adopted density function approximations suffer from delocalization error. In this work, by presuming a quantitative correspondence between the quasiparticle energies and the generalized Kohn–Sham orbital energies, and employing a previously developed global scaling correction approach, we achieve substantially improved prediction of molecular quasiparticle and excitation energies. In addition, we also extend our previous study on temporary anions in resonant states, which are associated with negative molecular electron affinities. The proposed approach does not require any explicit self-consistent field calculation on the excited-state species, and is thus highly efficient and convenient for practical purposes. 

Abstract Tropical precipitation change under global warming varies with season. The present study investigates the characteristics and cause of the seasonality in rainfall change. Diagnostically, tropical precipitation change is decomposed into thermodynamic and dynamic components. The thermodynamic component represents the wet-get-wetter effect and its seasonality is due mostly to that in the mean vertical velocity, especially in the monsoon regions. The dynamic component includes the warmer-get-wetter effect due to the spatial variations in sea surface temperature (SST) warming, while the seasonality is due to that of the climatological SST and can be largely reproduced by an atmospheric model forced with the monthly climatological SST plus the annual-mean SST warming pattern. In the eastern equatorial Pacific where the SST warming is locally enhanced; for example, rainfall increases only during the March–May season when the climatological SST is high enough for deep convection. To the extent that the seasonality of tropical precipitation change over oceans arises mostly from that of the climatological SST, the results support the notion that reducing model biases in climatology improves regional rainfall projections. 

Abstract The influence of eastern tropical Pacific (EPAC; 10°S–10°N, 140°–80°W) wind anomalies on El Niño is investigated using observations and model experiments. Extreme and moderate El Niños exhibit contrasting anomalous wind patterns in the EPAC during the peak and decay phases: westerly wind anomalies during extreme El Niño and southeasterly (southwesterly) wind anomalies south (north) of the equator during moderate El Niño. Experiments with an ocean general circulation model indicate that for extreme El Niño, the eastward intrusion of westerly wind anomalies contributes to the prolonged positive sea surface temperature (SST) anomalies in the eastern equatorial Pacific throughout boreal spring by weakened upwelling and horizontal advection. For moderate El Niño, by contrast, both the meridional and zonal anomalous winds over the EPAC are important in the rapid (slow) SST cooling south (north) of the equator through advection and wind–evaporation–SST feedback. Atmospheric model experiments confirm that these EPAC anomalous winds are primarily forced by tropical SST anomalies. The interplay between wind and SST anomalies suggests positive air–sea feedbacks over EPAC during the decay phase of El Niño. Ocean model results show that the frequency of extreme El Niño increases when EPAC wind anomalies are removed, suggesting the importance of EPAC winds for El Niño diversity.